Synthesis and Characterization of Meso-Alkynyl Corroles
Sprache des Vortragstitels:
Englisch
Original Tagungtitel:
International Conference on Porphyrins and Phthalocyanines ICPP-11 Virtual Meeting 2021
Sprache des Tagungstitel:
Englisch
Original Kurzfassung:
We present novel synthesis procedures to obtain a series of freebase and metal A2B- and meso-A3-ethynylcorroles. All reported ?-conjugated (metal) corroles exhibit significant peak broadening and extensive red shifts of UV-vis absorptions. The novel corroles may find application in catalysis, dye-sensitized solar cells and photodynamic therapy upon suitable modification. We will discuss the scope of our procedures and study the effect of electron- accepting and -donating substituents on the photophysical- and (electro)-chemical properties.
Sprache der Kurzfassung:
Englisch
Vortragstyp:
Hauptvortrag / Eingeladener Vortrag auf einer Tagung