Microwaves reveal the nanoscale ion intercalation and edge activity of 2D catalyst
Sprache des Titels:
Englisch
Original Kurzfassung:
The accelerated demand for electrochemical energy storage urges the need for new, sustainable, stable and lightweight materials able to store high energy densities rapidly and efficiently. Development of these functional materials requires specialized techniques that can provide a close insight into the electrochemical properties at the nanoscale.
For this reason, we have introduced the electrochemical scanning microwave microscopy (EC-SMM) enabling local measurement of electrochemical properties with nanometer spatial resolution and sensitivity down to atto-Ampere electrochemical currents. The
exceptional power of EC-SMM operated at radio frequency is exemplified here by the successful detection of the electrochemical activity and dynamics of molecularly thin NiCo(OH)2 flakes with a spatial resolution of 16 ± 1 nm, uncovering the location of
the active sites and providing atomistic details on the catalytic process that controls the electrocatalytic performance. Our results pinpoint the factors required to tune the thermodynamics of ion intercalation and to optimize the surface adsorption
Forschungs-